100-22-1 | N,N,N',N'-Tetramethyl-p-phenylenediamine

Packsize	Purity	Availability	Price	Discounted Price
5g	95%	in stock	$21.00	$15.00
10g	95%	in stock	$24.00	$17.00
25g	95%	in stock	$59.00	$42.00
50g	95%	in stock	$118.00	$83.00

Description

• Catalog Number: AB76655
• Chemical Name: N,N,N',N'-Tetramethyl-p-phenylenediamine
• CAS Number: 100-22-1
• Molecular Formula: C10H16N2
• Molecular Weight: 164.2474
• MDL Number: MFCD00008309
• SMILES: CN(c1ccc(cc1)N(C)C)C

Computed Properties

• Complexity: 108
• Covalently-Bonded Unit Count: 1
• Heavy Atom Count: 12
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 2
• XLogP3: 2.6

Literature

• Population-based in vitro hazard and concentration-response assessment of chemicals: the 1000 genomes high-throughput screening study.

  Environmental health perspectives 20150501

• Metabolomic analysis of arginine metabolism in acute hepatic injury in rats.

  The Journal of toxicological sciences 20140201

• An electrochemical thermometer: voltammetric measurement of temperature and its application to amperometric gas sensing.

  The Analyst 20120607

• Electrochemical estimation of diffusion anisotropy of N,N,N',N'-tetramethyl-para-phenylenediamine within the normal hexagonal lyotropic mesophase of Triton X 100/light water: when can the effects of cross-pseudophase electron transfer be neglected for partitioned reagents?

  The journal of physical chemistry. B 20110526

• Tetramethylphenylenediamine protects the isolated heart against ischaemia-induced apoptosis and reperfusion-induced necrosis.

  British journal of pharmacology 20110301

• Photoreactions and molecular dynamics of radical pairs in a reversed micelle studied by time-resolved measurements of EPR and magnetic field effect.

  The journal of physical chemistry. B 20101118

• Programmed cell death in plants: protective effect of phenolic compounds against chitosan and H2O2.

  Biochemistry. Biokhimiia 20100201

• Using N,N,N',N'-tetramethyl-p-phenylenediamine (TMPD) to assay cyclooxygenase activity in vitro.

  Methods in molecular biology (Clifton, N.J.) 20100101

• Viscosity dependence of rubrene fluorescence quenching by organic radicals via energy transfer.

  Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology 20091101

• Intercalation of stable organic radicals into layered saponite clay.

  Dalton transactions (Cambridge, England : 2003) 20091014

• Electrochemical one-electron oxidation of low-generation polyamidoamine-type dendrimers with a 1,4-phenylenediamine core.

  Chemphyschem : a European journal of chemical physics and physical chemistry 20090803

• Ultrasmall copper nanoparticles from a hydrophobically immobilized surfactant template.

  Nano letters 20090601

• SO(2) saturation of the room temperature ionic liquid [C(2)mim][NTf(2)] much reduces the activation energy for diffusion.

  The journal of physical chemistry. B 20090129

• Terameprocol, a methylated derivative of nordihydroguaiaretic acid, inhibits production of prostaglandins and several key inflammatory cytokines and chemokines.

  Journal of inflammation (London, England) 20090101

• Chronic exposure to the herbicide, atrazine, causes mitochondrial dysfunction and insulin resistance.

  PloS one 20090101

• Fatal Chromobacterium violaceum septicaemia in northern Laos, a modified oxidase test and post-mortem forensic family G6PD analysis.

  Annals of clinical microbiology and antimicrobials 20090101

• The fully oxidized form of the cytochrome bd quinol oxidase from E. coli does not participate in the catalytic cycle: direct evidence from rapid kinetics studies.

  FEBS letters 20081029

• Photoreactions of 1,4-naphthoquinone with lysozyme studied by laser flash photolysis and steady-state analysis.

  Journal of photochemistry and photobiology. B, Biology 20080821

• Effect of redox mediators on the flash-induced membrane potential generation in Mn-depleted photosystem II core particles.

  European biophysics journal : EBJ 20080701

• Training at high exercise intensity promotes qualitative adaptations of mitochondrial function in human skeletal muscle.

  Journal of applied physiology (Bethesda, Md. : 1985) 20080501

• Tetramethylphenylenediamine-induced hepatocyte cytotoxicity caused by lysosomal labilisation and redox cycling with oxygen activation.

  Chemico-biological interactions 20080310

• Ageing-induced alterations in lipid/phospholipid profiles of rat brain and liver mitochondria: implications for mitochondrial energy-linked functions.

  The Journal of membrane biology 20080101

• Antiinflammatory, analgesic and antipyretic activity of certain thiazolidinones.

  Indian journal of pharmaceutical sciences 20080101

• Wurster's crowns: a comparative study of ortho- and para-phenylenediamine-containing macrocyclic receptors.

  Inorganic chemistry 20071210

• The different behaviors of three oxidative mediators in probing the redox activities of the yeast Saccharomyces cerevisiae.

  Analytica chimica acta 20070730

• The oxidation/reduction kinetics of the plastoquinone pool controls the appearance of the I-peak in the O-J-I-P chlorophyll fluorescence rise: effects of various electron acceptors.

  Journal of photochemistry and photobiology. B, Biology 20070727

• Semiconductor behavior of a metal-organic framework (MOF).

  Chemistry (Weinheim an der Bergstrasse, Germany) 20070101

• A microfluidic channel flow cell for electrochemical ESR.

  The journal of physical chemistry. B 20061228

• Interaction of N,N,N',N'-tetramethyl-p-phenylenediamine with photosystem II as revealed by thermoluminescence: reduction of the higher oxidation states of the Mn cluster and displacement of plastoquinone from the Q(B) niche.

  Biochimica et biophysica acta 20061101

• Oxygenated edge plane sites slow the electron transfer of the ferro-/ferricyanide redox couple at graphite electrodes.

  Chemphyschem : a European journal of chemical physics and physical chemistry 20060612

• Studies of the inner reorganization energies of the cation radicals of 1,4-bis(dimethylamino)benzene, 9,10-bis(dimethylamino)anthracene, and 3,6-bis(dimethylamino)durene by photoelectron spectroscopy and reinterpretation of the mechanism of the electrochemical oxidation of the parent diamines.

  The journal of physical chemistry. A 20060504

• Arabidopsis thaliana fatty acid alpha-dioxygenase-1: evaluation of substrates, inhibitors and amino-terminal function.

  Plant physiology and biochemistry : PPB 20060101

• The presence of oxidized phosphatidylserine on Fas-mediated apoptotic cell surface.

  Biochimica et biophysica acta 20051001

• Cyanide-resistant respiration in Taenia crassiceps metacestode (cysticerci) is explained by the H2O2-producing side-reaction of respiratory complex I with O2.

  Parasitology international 20050901

• Radiolytically induced one-electron reduction of artemisinin in H2O/ethanol (1:1 v/v) solution: a pulse radiolysis study.

  International journal of radiation biology 20050401

• Spontaneous resolution in a halogen bonded supramolecular architecture.

  Chemical communications (Cambridge, England) 20050328

• Structural and functional alterations in mitochondrial membrane in picrotoxin-induced epileptic rat brain.

  Experimental neurology 20050301

• A comparative electrochemical study of diffusion in room temperature ionic liquid solvents versus acetonitrile.

  Chemphyschem : a European journal of chemical physics and physical chemistry 20050301

• Electron and hole transfer from indium phosphide quantum dots.

  The journal of physical chemistry. B 20050224

• Differences in kinetic properties of cytochrome oxidase in mitochondria from rat tissues. A comparative study.

  Zeitschrift fur Naturforschung. C, Journal of biosciences 20050101

• Arginine 391 in subunit I of the cytochrome bd quinol oxidase from Escherichia coli stabilizes the reduced form of the hemes and is essential for quinol oxidase activity.

  The Journal of biological chemistry 20041224

• Nitric oxide oscillations in Paracoccus denitrificans: the effects of environmental factors and of segregating nitrite reductase and nitric oxide reductase into separate cells.

  Archives of biochemistry and biophysics 20040915

• Studies on TMPD:TCNB; a donor-acceptor with room temperature paramagnetism and n-pi interaction.

  Molecules (Basel, Switzerland) 20040831

• Changes in polyphasic chlorophyll a fluorescence induction curve upon inhibition of donor or acceptor side of photosystem II in isolated thylakoids.

  Biochimica et biophysica acta 20040709

• Mitochondrial defects and heterogeneous cytochrome c release after cardiac cold ischemia and reperfusion.

  American journal of physiology. Heart and circulatory physiology 20040501

• Separation and quantitation of peroxidized phospholipids using high-performance thin-layer chromatography with tetramethyl-p-phenylenediamine detection.

  Analytical biochemistry 20040401

• Dynamics of positive charge carriers on Si chains of polysilanes.

  Journal of the American Chemical Society 20040324

• A cytochrome c-enhanced peroxidation reaction with potential use in screening dietary antioxidants.

  Journal of pharmaceutical and biomedical analysis 20040310

• Photoinduced interactions between oxidized and reduced lipoic acid and riboflavin (vitamin B2).

  Chemphyschem : a European journal of chemical physics and physical chemistry 20040123

• In situ evidence of an alternative oxidase and an uncoupling protein in the respiratory chain of Aspergillus fumigatus.

  The international journal of biochemistry & cell biology 20040101

• First estimation of C4-H bond dissociation energies of NADH and its radical cation in aqueous solution.

  Journal of the American Chemical Society 20031217

• N,N,N',N'-tetramethyl-p-phenylenediamine initiates the appearance of a well-resolved I peak in the kinetics of chlorophyll fluorescence rise in isolated thylakoids.

  Biochimica et biophysica acta 20031208

• Stimulation by surangin B of endogenous amino acid release from synaptosomes.

  Toxicon : official journal of the International Society on Toxinology 20030915

• Determination of residues of malachite green in aquatic animals.

  Journal of chromatography. B, Analytical technologies in the biomedical and life sciences 20030525

• Chemical reduction of 2,4,6-tricyano-1,3,5-triazine and 1,3,5-tricyanobenzene. Formation of novel 4,4',6,6'-Tetracyano-2,2'-bitriazine and its radical anion.

  The Journal of organic chemistry 20030502

• Determination of the C4-H bond dissociation energies of NADH models and their radical cations in acetonitrile.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20030217

• Effect of the first window of ischemic preconditioning on mitochondrial dysfunction following global cerebral ischemia.

  Mitochondrion 20021201

• Electron transfer oxidation of tryptophan and tyrosine by triplet states and oxidized radicals of flavin sensitizers: a laser flash photolysis study.

  Biochimica et biophysica acta 20020510

• Dimerization of organic free radicals in solution. 1. Temperature dependent measurements.

  Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 20020401

• Suramin inhibits respiration and induces membrane permeability transition in isolated rat liver mitochondria.

  Toxicology 20011201

• One-step synthesis and redox properties of dodecahydro-3a,9a-diazaperylene--the most easily oxidized p-phenylenediamine.

  Chemical communications (Cambridge, England) 20010921

• Flexible redox-active binuclear macrocycles formed via the weak-link approach and novel hemilabile ligands with N,N,N',N'-tetramethyl-1,4-phenylenediamine units.

  Inorganic chemistry 20010618

• Hydrogen peroxide inhibits photosynthetic electron transport in cells of cyanobacteria.

  Biochemistry. Biokhimiia 20010601

• Modular synthesis of pi-acceptor cyclophanes derived from 1,4,5,8-naphthalenetetracarboxylic diimide and 1,5-dinitronaphthalene.

  The Journal of organic chemistry 20010504

• Dysfunctional mitochondrial respiration in the wobbler mouse brain.

  Neuroscience letters 20010316

• Purification and some properties of ubiquinol oxidase from obligately chemolithotrophic iron-oxidizing bacterium, Thiobacillus ferrooxidans NASF-1.

  Bioscience, biotechnology, and biochemistry 20010101