2106-10-7 | Alpha-D-glucopyranosyl fluoride

Packsize	Purity	Availability	Price	Discounted Price
250mg	97%	in stock	$10.00	$7.00
1g	97%	in stock	$27.00	$19.00
5g	97%	in stock	$130.00	$91.00

Description

• Catalog Number: AF49504
• Chemical Name: Alpha-D-glucopyranosyl fluoride
• CAS Number: 2106-10-7
• Molecular Formula: C6H11FO5
• Molecular Weight: 182.1469
• MDL Number: MFCD00132903
• SMILES: OC[C@H]1O[C@H](F)[C@@H]([C@H]([C@@H]1O)O)O

Computed Properties

• Complexity: 155
• Covalently-Bonded Unit Count: 1
• Defined Atom Stereocenter Count: 5
• Heavy Atom Count: 12
• Hydrogen Bond Acceptor Count: 6
• Hydrogen Bond Donor Count: 4
• Rotatable Bond Count: 1
• XLogP3: -1.6

Literature

• Rice BGlu1 glycosynthase and wild type transglycosylation activities distinguished by cyclophellitol inhibition.

  Carbohydrate research 20120501

• Completely β-selective glycosylation using 3,6-O-(o-xylylene)-bridged axial-rich glucosyl fluoride.

  Journal of the American Chemical Society 20120425

• The role of the oligosaccharide binding cleft of rice BGlu1 in hydrolysis of cellooligosaccharides and in their synthesis by rice BGlu1 glycosynthase.

  Protein science : a publication of the Protein Society 20120301

• A stepwise solvent-promoted SNi reaction of α-D-glucopyranosyl fluoride: mechanistic implications for retaining glycosyltransferases.

  Journal of the American Chemical Society 20120118

• A β-(1,2)-glycosynthase and an attempted selection method for the directed evolution of glycosynthases.

  Biochemistry 20111129

• Mechanistic analysis of trehalose synthase from Mycobacterium smegmatis.

  The Journal of biological chemistry 20111014

• Aromatic interactions at the catalytic subsite of sucrose phosphorylase: their roles in enzymatic glucosyl transfer probed with Phe52→Ala and Phe52→Asn mutants.

  FEBS letters 20110204

• Peracetylated alpha-D-glucopyranosyl fluoride and peracetylated alpha-maltosyl fluoride.

  Acta crystallographica. Section C, Crystal structure communications 20100315

• Enzymatic synthesis of cello-oligosaccharides by rice BGlu1 {beta}-glucosidase glycosynthase mutants.

  Glycobiology 20070701

• Glycosynthase-mediated synthesis of glycosphingolipids.

  Journal of the American Chemical Society 20060517

• Overexpression and characterization of two unknown proteins, YicI and YihQ, originated from Escherichia coli.

  Protein expression and purification 20040901

• Crystal structure of the covalent intermediate of amylosucrase from Neisseria polysaccharea.

  Biochemistry 20040323

• alpha-1,4-Glucan lyase performs a trans-elimination via a nucleophilic displacement followed by a syn-elimination.

  Journal of the American Chemical Society 20020508

• Alpha-glucosidase mutant catalyzes 'alpha-glycosynthase'-type reaction.

  Bioscience, biotechnology, and biochemistry 20020401