21193-75-9 | D-Galactal

Packsize	Purity	Availability	Price	Discounted Price
1g	95%	in stock	$28.00	$19.00
5g	95%	in stock	$86.00	$60.00
25g	97%	in stock	$379.00	$266.00
100g	95%	in stock	$1,130.00	$791.00
500g	97%	in stock	$3,869.00	$2,708.00

Description

• Catalog Number: AI44863
• Chemical Name: D-Galactal
• CAS Number: 21193-75-9
• Molecular Formula: C6H10O4
• Molecular Weight: 146.1412
• MDL Number: MFCD00038067
• SMILES: OC[C@H]1OC=C[C@H]([C@H]1O)O

Computed Properties

• Complexity: 134
• Covalently-Bonded Unit Count: 1
• Defined Atom Stereocenter Count: 3
• Heavy Atom Count: 10
• Hydrogen Bond Acceptor Count: 4
• Hydrogen Bond Donor Count: 3
• Rotatable Bond Count: 1
• XLogP3: -1

Literature

• The synthesis of 2-deoxy-α-D-glycosides from D-glycals catalyzed by TMSI and PPh3.

  Carbohydrate research 20120901

• Measurement of the activity of individual subunits of single molecules of the tetrameric enzyme β-galactosidase.

  Analytical chemistry 20120515

• Sequential directed epoxydation-acidolysis from glycals with MCPBA. A flexible approach to protected glycosyl donors.

  The Journal of organic chemistry 20111202

• Convergent synthesis of the tetrasaccharide repeating unit corresponding to the O-antigen of the verotoxin-producing Escherichia coli O176.

  Glycoconjugate journal 20111201

• Stereodivergent synthesis of diastereoisomeric carba analogs of glycal-derived vinyl epoxides: a new access to carbasugars.

  Chirality 20111001

• A short and highly efficient synthesis of L-ristosamine and L-epi-daunosamine glycosides.

  Organic letters 20110218

• Stereoselective C-glycosidations with achiral and enantioenriched allenylsilanes.

  Organic letters 20101015

• Synthesis of gamma-aminobutyric acid analogs based on carbohydrate scaffolds.

  Carbohydrate research 20100616

• Regio- and stereocontrolled selective debenzylation and substitution reactions of C-2 formyl glycals. Application in the synthesis of constrained beta-sugar amino acids.

  The Journal of organic chemistry 20090807

• Attempts to improve the overall stereoselectivity of the Ireland-Claisen rearrangement.

  Organic letters 20090115

• Synthesis and self-assembly of glycal-based bolaforms.

  The Journal of organic chemistry 20081121

• The use of tri-O-acetyl-D-glucal and -D-galactal in the synthesis of omega-aminoalkyl 2-deoxy- and 2,3-dideoxy-d-hexopyranosides.

  Carbohydrate research 20081013

• Synthesis of new 2-phosphono-alpha-D-glycoside derivatives by stereoselective oxa-Michael addition to a D-galacto derived enone.

  Carbohydrate research 20080519

• 2-Nitroglycals: versatile intermediates for efficient and highly stereoselective base-catalyzed glycoside bond formations.

  Nature protocols 20080101

• Synthesis and anti-inflammatory activity of N-phthalimidomethyl 2,3-dideoxy- and 2,3-unsaturated glycosides.

  Carbohydrate research 20070702

• Glycal glycosylation and 2-nitroglycal concatenation, a powerful combination for mucin core structure synthesis.

  The Journal of organic chemistry 20070608

• Synthesis of a sialic acid alpha(2-3) galactose building block and its use in a linear synthesis of sialyl Lewis X.

  Organic letters 20070426

• Direct epoxidation of D-glucal and D-galactal derivatives with in situ generated DMDO.

  Carbohydrate research 20061127

• Antiproliferation and apoptosis induced by C-glycosides in human leukemia cancer cells.

  Bioorganic & medicinal chemistry letters 20060815

• Superoxide dismutase-like activity of cobalt(II) complexes based on a sugar platform.

  Chemical communications (Cambridge, England) 20051121

• Protic acid (HClO4 supported on silica gel)-mediated synthesis of 2,3-unsaturated-O-glucosides and a chiral furan diol from 2,3-glycals.

  The Journal of organic chemistry 20040903

• Reinvestigation of the mercuration-demercuration reaction on alkylated glycals: an improved method for the preparation of 2,3-dideoxy-alpha,beta-unsaturated carbohydrate enals.

  Carbohydrate research 20040802

• A novel sulfonamidoglycosylation of glycals.

  Organic letters 20031113

• Synthetic studies towards the tunicamycins and analogues based on diazo chemistry. Total synthesis of tunicaminyl uracil.

  Organic & biomolecular chemistry 20031107

• Totally stereoselective synthesis of 1,3-disaccharides through Diels-Alder reactions.

  The Journal of organic chemistry 20031031

• The use of tri-O-acetyl-D-glucal and -D-galactal in the synthesis of 3-acetamido-2,3-dideoxyhexopyranoses and -hexopyranosides.

  Carbohydrate research 20021105

• Addition of malonyl radicals to glycals with C-1 acceptor groups: remarkable influence of the substituents on the product distribution.

  Chemical communications (Cambridge, England) 20020621

• Higher acyclic nitrogen containing deoxy sugar derivatives: a new lead in the generation of antimycobacterial chemotherapeutics.

  Bioorganic & medicinal chemistry 20020601

• [Clinical and experimental study of shuangcao tuihuang granule-1 in treating severe jaundice of acute icterohepatitis].

  Zhongguo Zhong xi yi jie he za zhi Zhongguo Zhongxiyi jiehe zazhi = Chinese journal of integrated traditional and Western medicine 20010901

• Protection of pig kidney (PK15) cells from the cytotoxic effect of anti-pig antibodies by alpha-galactosyl oligosaccharides.

  Transplantation 19940327