536-80-1 | Iodosobenzene

Packsize	Purity	Availability	Price	Discounted Price
1g	98%	in stock	$106.00	$75.00
5g	>95.0%(T)	in stock	$224.00	$157.00
25g	>95.0%(T)	in stock	$653.00	$457.00

Description

• Catalog Number: AB49212
• Chemical Name: Iodosobenzene
• CAS Number: 536-80-1
• Molecular Formula: C6H5IO
• Molecular Weight: 220.0078
• MDL Number: MFCD00039507
• SMILES: O=[I]c1ccccc1
• NSC Number: 406477

Computed Properties

• Complexity: 76.6
• Covalently-Bonded Unit Count: 1
• Heavy Atom Count: 8
• Hydrogen Bond Acceptor Count: 1
• XLogP3: 2

Literature

• Synthesis of highly substituted oxazoles through iodine(III)-mediated reactions of ketones with nitriles.

  Molecules (Basel, Switzerland) 20120913

• Cytochrome P450-type hydroxylation and epoxidation in a tyrosine-liganded hemoprotein, catalase-related allene oxide synthase.

  The Journal of biological chemistry 20120713

• A practical and convenient fluorination of 1,3-dicarbonyl compounds using aqueous HF in the presence of iodosylbenzene.

  Organic letters 20110506

• Stereoselective synthesis of 2-carbamoyl-2-cyanocyclopropanecarboxylates by tandem oxidative cyclization and neighboring group-assisted decarboxylation.

  The Journal of organic chemistry 20101015

• Characterization of the peroxidase mechanism upon reaction of prostacyclin synthase with peracetic acid. Identification of a tyrosyl radical intermediate.

  Biochemistry 20090210

• Synthesis, characterization, and reactivities of manganese(V)-oxo porphyrin complexes.

  Journal of the American Chemical Society 20070207

• Mechanistic studies on peroxide activation by a water-soluble iron(III)-porphyrin: implications for O-O bond activation in aqueous and nonaqueous solvents.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20070101

• Formation of the active species of cytochrome p450 by using iodosylbenzene: a case for spin-selective reactivity.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20070101

• [Hydroxy(tosyloxy)iodo]benzene mediated alpha-azidation of ketones.

  Molecules (Basel, Switzerland) 20060714

• Oxidation of 3-hydroxypiperidines with iodosylbenzene in water: tandem oxidative Grob fragmentation-cyclization reaction.

  Chemical & pharmaceutical bulletin 20040901

• Incorporation of an oxygen from water into troglitazone quinone by cytochrome P450 and myeloperoxidase.

  Drug metabolism and disposition: the biological fate of chemicals 20040401

• Reversible formation of iodosylbenzene-iron porphyrin intermediates in the reaction of oxoiron(IV) porphyrin pi-cation radicals and iodobenzene.

  Angewandte Chemie (International ed. in English) 20030103

• Study of the catalytic behavior of montmorillonite/iron(III) and Mn(III) cationic porphyrins.

  Journal of colloid and interface science 20021001

• Regioselective biomimetic oxidation of etodolac with iodosylbenzene catalyzed by halogenated and perhalogenated metalloporphyrins in dichloromethane.

  Chemical & pharmaceutical bulletin 20011001

• Chromium(III)-mediated structural modification of glycoprotein: impact of the ligand and the oxidants.

  Biochemical and biophysical research communications 20010727

• Spectral studies of tert-butyl isothiocyanate-inactivated P450 2E1.

  Biochemistry 20010619