6737-42-4 | 1,3-Bis(diphenylphosphino)propane

Packsize	Purity	Availability	Price	Discounted Price
5g	97%	in stock	$6.00	$4.00
10g	97%	in stock	$7.00	$5.00
25g	97%	in stock	$15.00	$11.00
100g	97%	in stock	$58.00	$41.00
500g	97%	in stock	$155.00	$109.00

Description

• Catalog Number: AB43126
• Chemical Name: 1,3-Bis(diphenylphosphino)propane
• CAS Number: 6737-42-4
• Molecular Formula: C27H26P2
• Molecular Weight: 412.4429
• MDL Number: MFCD00003050
• SMILES: C(CP(c1ccccc1)c1ccccc1)CP(c1ccccc1)c1ccccc1
• NSC Number: 193753

Computed Properties

• Complexity: 350
• Covalently-Bonded Unit Count: 1
• Heavy Atom Count: 29
• Rotatable Bond Count: 8
• XLogP3: 6.2

Literature

• Bis[1,3-bis-(diphenyl-phosphan-yl)propane]-copper(I) tetra-chlorido-gallate(III).

  Acta crystallographica. Section E, Structure reports online 20120701

• Charge retention by gold clusters on surfaces prepared using soft landing of mass selected ions.

  ACS nano 20120124

• A selective intramolecular 5-exo-dig or 6-endo-dig cyclization en route to 2-furanone or 2-pyrone containing tricyclic scaffolds.

  The Journal of organic chemistry 20111202

• [1,3-Bis(diphenyl-phosphan-yl)propane-κP,P'](1,10-phenanthroline-κN,N')copper(I) perchlorate.

  Acta crystallographica. Section E, Structure reports online 20111201

• Synthesis of functionalized cinnamaldehyde derivatives by an oxidative Heck reaction and their use as starting materials for preparation of Mycobacterium tuberculosis 1-deoxy-D-xylulose-5-phosphate reductoisomerase inhibitors.

  The Journal of organic chemistry 20111104

• Poly[bis-[μ-1,3-bis-(diphenyl-phosphan-yl)propane-κP:P']-di-μ-thio-cyanato-κS:N;κN:S-disilver(I)].

  Acta crystallographica. Section E, Structure reports online 20111101

• Reaction mechanism governing formation of 1,3-bis(diphenylphosphino)propane-protected gold nanoclusters.

  Inorganic chemistry 20111017

• Preparation of η2-complexes of fullerenes by reduction. Crystal structure and optical properties of {Ni(dppp)·(η2-C70)}·(C6H4Cl2)0.5.

  Dalton transactions (Cambridge, England : 2003) 20110928

• catena-Poly[[[μ-1,3-bis(diphenylphosphanyl)propane-κ2P:P'][O-ethyl (4-methoxyphenyl)phosphonodithioato-κ2S,S']silver(I)] chloroform monosolvate].

  Acta crystallographica. Section C, Crystal structure communications 20110901

• Multimetallic complexes of group 10 and 11 metals based on polydentate dithiocarbamate ligands.

  Dalton transactions (Cambridge, England : 2003) 20110614

• Nickel-catalyzed cross-coupling of phenols and arylboronic acids through an in situ phenol activation mediated by PyBroP.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20110328

• Reactions of a gold(I) thiolate complex [Au(Tab)(2)](2)(PF(6))(2) (Tab = 4-(trimethylammonio)benzenethiolate) with diphosphine ligands.

  Dalton transactions (Cambridge, England : 2003) 20110121

• Diversity-oriented synthesis based on the DPPP-catalyzed mixed double-Michael reactions of electron-deficient acetylenes and β-amino alcohols.

  Molecules (Basel, Switzerland) 20110101

• Synthesis and spectrosopic identification of hybrid 3-(triethoxysilyl)propylamine phosphine ruthenium(II) complexes.

  Molecules (Basel, Switzerland) 20100517

• Efficient synthesis of alkyl aryl ketones & ketals via palladium-catalyzed regioselective arylation of vinyl ethers.

  Organic & biomolecular chemistry 20100507

• Synthesis, characterization and cytotoxic activities of the [RuCl2(NO)(dppp)(L)]PF6 complexes.

  Journal of inorganic biochemistry 20100501

• Diphosphine-catalyzed mixed double-Michael reaction: a unified synthesis of indolines, dihydropyrrolopyridines, benzimidazolines, tetrahydroquinolines, tetrahydroisoquinolines, dihydrobenzo-1,4-oxazines, and dihydrobenzo-3,1-oxazines.

  Organic letters 20100305

• Tertiary carbinamine synthesis by rhodium-catalyzed [3+2] annulation of N-unsubstituted aromatic ketimines and alkynes.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20100222

• Sterically-directed consecutive and size-selective self-assembly of palladium diphosphane complexes with an Ar-BIAN ligand: unexpected formation of pentameric and hexameric aggregates.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20091012

• Externally initiated regioregular P3HT with controlled molecular weight and narrow polydispersity.

  Journal of the American Chemical Society 20090916

• Aromatic C-F activation by complexes containing the {Pt2S2} core via nucleophilic substitution: a combined experimental and theoretical study.

  Dalton transactions (Cambridge, England : 2003) 20090814

• Regioselective Heck vinylation of electron-rich olefins with vinyl halides: is the neutral pathway in operation?

  The Journal of organic chemistry 20090403

• Iron-catalysed Negishi coupling of benzyl halides and phosphates.

  Chemical communications (Cambridge, England) 20090207

• Mechanistic insights into the rhodium-catalyzed intramolecular ketone hydroacylation.

  Journal of the American Chemical Society 20090128

• Characterization of self-assembled metallodendrimers in solution, in the gas phase, and at air/solid interfaces.

  Small (Weinheim an der Bergstrasse, Germany) 20081001

• [1,3-Bis(diphenyl-phosphino)propane-κP,P']diiodido(perfluoro-propyl)rhodium(III) dichloro-methane solvate.

  Acta crystallographica. Section E, Structure reports online 20081001

• Metallo-supramolecular self-assembly: the case of triangle-square equilibria.

  Inorganic chemistry 20080901

• Bis[1,3-bis-(diphenyl-phosphino)propane-κP:P']silver(I) bis-(chloro-difluoro-acetato-κO)triphenyl-stannate(IV).

  Acta crystallographica. Section E, Structure reports online 20080501

• Reaction chemistry of complexes containing Pt--H, Pt--SH, or Pt--S fragments: from their apparent simplicity to the maze of reactions underlying their interconversion.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20070101

• Development of potential manufacturing routes for substituted thiophenes--preparation of halogenated 2-thiophenecarboxylic acid derivatives as building blocks for a new family of 2,6-dihaloaryl 1,2,4-triazole insecticides.

  Beilstein journal of organic chemistry 20070101

• Regioselective Heck arylation of unsaturated alcohols by palladium catalysis in ionic liquid.

  Chemical communications (Cambridge, England) 20060914

• Rhodium(I)-catalyzed carboxylation of aryl- and alkenylboronic esters with CO2.

  Journal of the American Chemical Society 20060712

• Structural variations and spectroscopic properties of luminescent mono- and multinuclear silver(I) and copper(I) complexes bearing phosphine and cyanide ligands.

  Inorganic chemistry 20050307

• Cobalt-catalyzed cross-coupling reactions of alkyl halides with allylic and benzylic Grignard reagents and their application to tandem radical cyclization/cross-coupling reactions.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20041105

• Self-assembly of flexible supramolecular metallacyclic ensembles: structures and adsorption properties of their nanoporous crystalline frameworks.

  Journal of the American Chemical Society 20040901

• Palladium-catalyzed alkylation of vinyl oxiranes with substituted allenes. Direct access to bifunctionalized allylic alcohols.

  The Journal of organic chemistry 20040709

• Hydrosilylation of alkynes with a cationic rhodium species formed in an anionic micellar system.

  Organic letters 20040624

• Facile palladium-catalysed synthesis of 1-aryl-1H-indazoles from 2-bromobenzaldehydes and arylhydrazines.

  Chemical communications (Cambridge, England) 20040107

• Square-planar coordinated polyanions of palladium, platinum, and gold stannaborate [SnB11H11]2- coordination chemistry.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20030922

• A new regioselective Heck vinylation with enamides. Synthesis and investigation of fluorous-tagged bidentate ligands for fast separation.

  The Journal of organic chemistry 20030822

• A novel palladium-catalyzed synthesis of 1,2-dihydroquinoxalines and 3,4-dihydroquinoxalinones.

  Organic letters 20020418

• Gold(I) macrocycles and topologically chiral [2]catenanes.

  Journal of the American Chemical Society 20020417

• Aryl-aryl coupling reaction using a novel and highly active palladium reagent prepared from Pd(OAc)2, 1,3-bis[diphenylphosphino]propane (DPPP), and Bu3P.

  Chemical & pharmaceutical bulletin 20020401

• [Bis(diphenylphosphino)methane][1,3-bis(diphenylphosphino)propane]platinum(II) dibromide.

  Acta crystallographica. Section C, Crystal structure communications 20011101

• A meso-helical coordination polymer from achiral dinuclear [Cu2(H3CCN)2(micro-pydz)3][PF6]2 and 1,3-bis(diphenylphosphanyl)propane-synthesis and crystal structure of 1 to infinity Cu(mu-pydz)2][PF6 (pydz=pyridazine).

  Chemistry (Weinheim an der Bergstrasse, Germany) 20010917

• Iridium-catalyzed transfer hydrogenation of alpha,beta-unsaturated and saturated carbonyl compounds with 2-propanol.

  The Journal of organic chemistry 20010629

• Heterobimetallic, cubane-like Mo(3)S(4)M' cluster cores containing the noble metals M' = Ru, Os, Rh, Ir. Unprecedented tri(mu-carbonyl) bridge between ruthenium atoms in [(eta(5)-Cp')(3)Mo(3)S(4)Ru)2(mu-CO)3]2+.

  Inorganic chemistry 20010618