754-05-2 | Vinyltrimethylsilane

Packsize	Purity	Availability	Price	Discounted Price
1g	95%	in stock	$26.00	$18.00
5g	98%(GC)	in stock	$44.00	$31.00
25g	95%	in stock	$134.00	$94.00

Description

• Catalog Number: AB47280
• Chemical Name: Vinyltrimethylsilane
• CAS Number: 754-05-2
• Molecular Formula: C5H12Si
• Molecular Weight: 100.2343
• MDL Number: MFCD00008606
• SMILES: C=C[Si](C)(C)C
• NSC Number: 93553

Computed Properties

• Complexity: 49.4
• Covalently-Bonded Unit Count: 1
• Heavy Atom Count: 6
• Rotatable Bond Count: 1

Literature

• Iron-catalyzed unexpected easy access to stereodefined trimethylsilyl vinyl ketenes.

  Organic letters 20120817

• (E)-9-(2-iodovinyl)-9H-carbazole: a new coupling reagent for the synthesis of π-conjugated carbazoles.

  Organic letters 20110415

• Room-temperature regioselective C-H/olefin coupling of aromatic ketones using an activated ruthenium catalyst with a carbonyl ligand and structural elucidation of key intermediates.

  Journal of the American Chemical Society 20101222

• Development of a general, sequential, ring-closing metathesis/intramolecular cross-coupling reaction for the synthesis of polyunsaturated macrolactones.

  Journal of the American Chemical Society 20100825

• Cobalt-catalyzed regio- and stereoselective intermolecular enyne coupling: an efficient route to 1,3-diene derivatives.

  Chemical communications (Cambridge, England) 20100321

• Quantum chemical studies on substitution effects within silyl group in the silylative coupling of olefins.

  Journal of molecular modeling 20100301

• Palladium-catalyzed cyclopropanation of alkenyl silanes by diazoalkanes: evidence for a Pd(0) mechanism.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20090101

• Why does fluoride anion accelerate transmetalation between vinylsilane and palladium(II)-vinyl complex? Theoretical study.

  Journal of the American Chemical Society 20081001

• Scope and mechanism of the intermolecular addition of aromatic aldehydes to olefins catalyzed by Rh(I) olefin complexes.

  Journal of the American Chemical Society 20070221

• Part 3. Triethylborane-air: a suitable initiator for intermolecular radical additions of S-2-oxoalkyl-thionocarbonates (S-xanthates) to olefins.

  Beilstein journal of organic chemistry 20070101

• Cobalt-mediated cross-coupling reactions of primary and secondary alkyl halides with 1-(trimethylsilyl)ethenyl- and 2-trimethylsilylethynylmagnesium reagents.

  Organic letters 20060706

• Vinyltrimethylsilane (VTMS) as a probe of chemical reactivity of a TiCN diffusion barrier-covered silicon surface.

  The journal of physical chemistry. B 20060316

• Complex thermal chemistry of vinyltrimethylsilane on Si(100)-2x1.

  The journal of physical chemistry. B 20050505

• Photochemical reactions of [CH2(eta5-C5H4)2][Rh(C2H4)2]2 with silanes: evidence for Si-C and C-H activation pathways.

  Dalton transactions (Cambridge, England : 2003) 20050221

• Cationic carbohydroxylation of alkenes and alkynes using the cation pool method.

  Organic letters 20040805

• Synthesis and structure of polymeric networks of silver hexafluoroacetylacetonate complexes of THF, toluene, and vinyltrimethylsilane.

  Inorganic chemistry 20031215

• Preparation of optically pure propargylic and allylic alcohols from 2-(trimethylsilyl)vinyl sulfoxides as a chiral ethynyl anion synthon: computational studies on elimination reaction of 2-(trimethylsilyl)vinyl sulfoxides.

  The Journal of organic chemistry 20020208

• Trimethylsilyl group migrations in cryogenic ozonolysis of trimethylsilylethene: evidence for nonconcerted primary ozonide decomposition pathway.

  The Journal of organic chemistry 20011019