88189-03-1 | Bismuth(iii) trifluoromethanesulfonate

Packsize	Purity	Availability	Price	Discounted Price
250mg	98%	in stock	$8.00	$6.00
1g	98%	in stock	$10.00	$7.00
5g	98%	in stock	$13.00	$9.00
10g	98%	in stock	$18.00	$13.00
25g	95%	in stock	$21.00	$15.00
100g	95%	in stock	$78.00	$55.00
500g	95%	in stock	$384.00	$269.00

Description

• Catalog Number: AB45649
• Chemical Name: Bismuth(iii) trifluoromethanesulfonate
• CAS Number: 88189-03-1
• Molecular Formula: C3BiF9O9S3
• Molecular Weight: 656.1877
• MDL Number: MFCD08272314
• SMILES: FC(S(=O)(=O)[O-])(F)F.FC(S(=O)(=O)[O-])(F)F.FC(S(=O)(=O)[O-])(F)F.[Bi+3]

Computed Properties

• Complexity: 145
• Covalently-Bonded Unit Count: 4
• Heavy Atom Count: 25
• Hydrogen Bond Acceptor Count: 18

Literature

• Bi(OTf)3-, TfOH-, and TMSOTf-mediated, one-pot epoxide rearrangement, addition, and intramolecular silyl-modified Sakurai (ISMS) cascade toward dihydropyrans: comparison of catalysts and role of Bi(OTf)3.

  The Journal of organic chemistry 20111118

• Bi(OTf)3-catalysed prenylation of electron-rich aryl ethers and phenols with isoprene: a direct route to prenylated derivatives.

  Organic & biomolecular chemistry 20110721

• Biomimetic cationic polyannulation reaction catalyzed by Bi(OTf)3: cyclization of 1,6-dienes, 1,6,10-trienes, and aryl polyenes.

  Organic letters 20110701

• Synthesis of chiral 1-substituted tetrahydroisoquinolines by the intramolecular 1,3-chirality transfer reaction catalyzed by Bi(OTf)3.

  The Journal of organic chemistry 20110401

• Efficient conversion of triacylglycerols and fatty acids to biodiesel in a microwave reactor using metal triflate catalysts.

  Organic & biomolecular chemistry 20101021

• Bismuth(III) triflate-catalyzed direct conversion of corticosteroids into highly functionalized 17-ketosteroids by cleavage of the C17-dihydroxyacetone side chain.

  The Journal of organic chemistry 20091106

• Multicatalytic synthesis of complex tetrahydrofurans involving bismuth(III) triflate catalyzed intramolecular hydroalkoxylation of unactivated olefins.

  Organic letters 20090319

• Bismuth triflate-catalyzed Wagner-Meerwein rearrangement in terpenes. Application to the synthesis of the 18alpha-oleanane core and A-neo-18alpha-oleanene compounds from lupanes.

  Organic & biomolecular chemistry 20090207

• An efficient and mild bismuth triflate-catalysed three-component Mannich-type reaction.

  Organic & biomolecular chemistry 20071007

• New entries to water-compatible Lewis acids.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20060807

• Bismuth triflate-chiral bipyridine complexes as water-compatible chiral Lewis acids.

  Organic letters 20051013

• Bismuth compounds in organic synthesis. A one-pot synthesis of homoallyl ethers and homoallyl acetates from aldehydes catalyzed by bismuth triflate.

  The Journal of organic chemistry 20050318

• Glycosylation of sialyl acetates with a novel catalyst combination: bismuth triflate and BF3.OEt2 system.

  Bioorganic & medicinal chemistry 20030717

• Highly powerful and practical acylation of alcohols with acid anhydride catalyzed by Bi(OTf)(3).

  The Journal of organic chemistry 20011228