89343-06-6 | (Triisopropylsilyl)acetylene

Packsize	Purity	Availability	Price	Discounted Price
1g	97%	in stock	$10.00	$7.00
5g	97%	in stock	$13.00	$9.00
10g	97%	in stock	$18.00	$12.00
25g	97%	in stock	$38.00	$26.00
100g	97%	in stock	$133.00	$93.00
250g	97%	in stock	$295.00	$206.00
500g	97%	in stock	$516.00	$361.00

Description

• Catalog Number: AB46153
• Chemical Name: (Triisopropylsilyl)acetylene
• CAS Number: 89343-06-6
• Molecular Formula: C11H22Si
• Molecular Weight: 182.3779
• MDL Number: MFCD00075452
• SMILES: CC([Si](C(C)C)(C(C)C)C#C)C

Computed Properties

• Complexity: 159
• Covalently-Bonded Unit Count: 1
• Heavy Atom Count: 12
• Rotatable Bond Count: 4

Literature

• Substituent effects on the electronic characteristics of pentacene derivatives for organic electronic devices: dioxolane-substituted pentacene derivatives with triisopropylsilylethynyl functional groups.

  Journal of the American Chemical Society 20120829

• Unexpected formation of a cyclic vinylene sulfate in the synthesis of ethynyl-substituted acenes.

  Chemical communications (Cambridge, England) 20120707

• Highly chemoselective nickel-catalyzed three-component cross-trimerization between two distinct terminal alkynes and an internal alkyne.

  Organic letters 20110107

• Rhodium-catalyzed asymmetric conjugate alkynylation of nitroalkenes.

  Chemical communications (Cambridge, England) 20100928

• A stable heptacene derivative substituted with electron-deficient trifluoromethylphenyl and triisopropylsilylethynyl groups.

  Organic letters 20100806

• (Butane-1,3-diyne-1,4-diyl)bis-(tri-isopropyl-silane).

  Acta crystallographica. Section E, Structure reports online 20100801

• Efficient preparation of photoswitchable dithienylethene-linker-conjugates by palladium-catalyzed coupling reactions of terminal alkynes with thienyl chlorides and other aryl halides.

  Chemistry, an Asian journal 20100503

• Electronic properties of pentacene versus triisopropylsilylethynyl-substituted pentacene: environment-dependent effects of the silyl substituent.

  Journal of the American Chemical Society 20100120

• Nickel-catalyzed, regio- and stereoselective hydroalkynylation of methylenecyclopropanes with retention of the cyclopropane ring, leading to the synthesis of 1-methyl-1-alkynylcyclopropanes.

  Journal of the American Chemical Society 20090415

• Nickel-catalyzed highly regio- and stereoselective cross-trimerization between triisopropylsilylacetylene and internal alkynes leading to 1,3-diene-5-ynes.

  Journal of the American Chemical Society 20090311

• Nickel-catalyzed regioselective hydroalkynylation of styrenes: improved catalyst system, reaction scope, and mechanism.

  Organic letters 20090205

• Wiring terpyridine: approaches to alkynylthienyl 2,2':6',2''-terpyridines.

  Dalton transactions (Cambridge, England : 2003) 20081221

• Rhodium-catalyzed asymmetric ring-opening alkynylation of azabenzonorbornadienes.

  Organic letters 20080918

• Rhodium-catalyzed (E)-selective cross-dimerization of terminal alkynes.

  Chemical communications (Cambridge, England) 20080807

• Nickel-catalyzed addition of C-H bonds of terminal alkynes to 1,3-dienes and styrenes.

  Journal of the American Chemical Society 20080423

• Synthesis of highly soluble and oxidatively stable tetraceno[2,3-b]thiophenes and pentacenes.

  The Journal of organic chemistry 20070817

• Palladium-catalyzed selective cross-addition of triisopropylsilylacetylene to internal and terminal unactivated alkynes.

  Organic letters 20070719

• Synthetic chlorins bearing auxochromes at the 3- and 13-positions.

  The Journal of organic chemistry 20060526

• Structurally characterized hetero-oligopolyphenylenes: synthetic advances toward next-generation heterosuperbenzenes.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20060403