96556-05-7 | 1,4,7-Trimethyl-1,4,7-triazacyclononane

Packsize	Purity	Availability	Price	Discounted Price
1g	97% (stabilized with NaHCO3)	in stock	$10.00	$7.00
5g	97% (stabilized with NaHCO3)	in stock	$16.00	$11.00
10g	97% (stabilized with NaHCO3)	in stock	$19.00	$14.00
25g	95%	in stock	$24.00	$17.00

Description

• Catalog Number: AB57403
• Chemical Name: 1,4,7-Trimethyl-1,4,7-triazacyclononane
• CAS Number: 96556-05-7
• Molecular Formula: C9H21N3
• Molecular Weight: 171.2831
• MDL Number: MFCD00012359
• SMILES: CN1CCN(C)CCN(CC1)C

Computed Properties

• Complexity: 91.2
• Covalently-Bonded Unit Count: 1
• Heavy Atom Count: 12
• Hydrogen Bond Acceptor Count: 3
• XLogP3: -0.4

Literature

• A mononuclear ruthenium complex showing multiple proton-coupled electron transfer toward multi-electron transfer reactions.

  Dalton transactions (Cambridge, England : 2003) 20121114

• Manganese triazacyclononane oxidation catalysts grafted under reaction conditions on solid cocatalytic supports.

  Journal of the American Chemical Society 20111123

• Syntheses, structures, and magnetic properties of low-dimensional heterometallic complexes based on the versatile building block [(Tp)Cr(CN)3]-.

  Inorganic chemistry 20110905

• Structure and dynamics of α-aryl amide and ketone enolates: THF, PMDTA, TMTAN, HMPA, and crypt-solvated lithium enolates, and comparison with phosphazenium analogues.

  The Journal of organic chemistry 20100917

• Hydrolytic cleavage of double-strand DNA by the water-soluble dicobalt(III) complexes of 1,4,7-triazacyclononane-N-acetate.

  Journal of inorganic biochemistry 20100901

• Eicosanuclear cluster [Cu(13)W(7)] of copper-octacyanotungstate bimetallic assembly: synthesis, structure, and magnetic properties.

  Inorganic chemistry 20100405

• trans-[Os(III)(salen)(CN)(2)](-): a new paramagnetic building block for the construction of molecule-based magnetic materials.

  Inorganic chemistry 20100215

• Metal-complexes as ligands to generate asymmetric homo- and heterodinuclear M(A)(III)M(B)(II) species: a magneto-structural and spectroscopic comparison of imidazole-N versus pyridine-N.

  Inorganic chemistry 20100118

• X-ray emission spectroscopy to study ligand valence orbitals in Mn coordination complexes.

  Journal of the American Chemical Society 20090916

• Aging accelerates the progression and manifestation of seizures in post-traumatic model of epilepsy.

  Neuroscience letters 20090403

• Reduction of nitrous oxide to dinitrogen by a mixed valent tricopper-disulfido cluster.

  Journal of the American Chemical Society 20090304

• Effect of additives on chemoselectivity and diastereoselectivity in the catalytic epoxidation of chiral allylic alcohols with hydrogen peroxide and binuclear manganese complexes.

  The Journal of organic chemistry 20090206

• Synthesis, spectroscopic and thermal investigations of solid charge-transfer complexes of 1,4,7-trimethyl-1,4,7-triazacyclononane and the acceptors iodine, TCNE, TCNQ and chloranil.

  Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 20081215

• The role of salicylic acid, L-ascorbic acid and oxalic acid in promoting the oxidation of alkenes with H2O2 catalysed by [MnIV2(O)3(tmtacn)2]2+.

  Dalton transactions (Cambridge, England : 2003) 20081128

• Homogeneous [Ru(III)(Me3tacn)Cl3]-catalyzed alkene cis-dihydroxylation with aqueous hydrogen peroxide.

  Chemistry, an Asian journal 20080104

• Rational synthesis of a heterotetranuclear CrIII2CuII2 species using a metaloximate as a building block. A magnetostructural study.

  Dalton transactions (Cambridge, England : 2003) 20071107

• Spectroscopic investigation of the charge-transfer interactions between 1,4,7-trimethyl-1,4,7-triazacyclononane and the acceptors iodine, TCNE, TCNQ and chloranil.

  Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 20071101

• Mechanism of cis-dihydroxylation and epoxidation of alkenes by highly H(2)O(2) efficient dinuclear manganese catalysts.

  Inorganic chemistry 20070806

• Ruthenium-catalyzed oxidation of alkenes, alkynes, and alcohols to organic acids with aqueous hydrogen peroxide.

  Chemistry, an Asian journal 20060918

• A remarkable inversion of structure-activity dependence on imido N-substituents with varying co-ligand topology and the synthesis of a new borate-free zwitterionic polymerisation catalyst.

  Chemical communications (Cambridge, England) 20060128

• Alkene cis-dihydroxylation by [(Me3tacn)(CF3CO2)RuVI O2)]ClO4(Me(3)tacn = 1,4,7-Trimethyl-1,4,7-triazacyclononane): structural characterization of [3 + 2] cycloadducts and kinetic studies.

  Journal of the American Chemical Society 20051019

• Kinetics and mechanism of hydrolysis of a model phosphate diester by [Cu(Me3tacn)(OH2)2]2+ (Me3tacn = 1,4,7-trimethyl-1,4,7-triazacyclononane).

  Inorganic chemistry 20050221

• Reactions of (di)manganese carbonyl ions with 1,4,7-trimethyl-1,4,7-triazacyclononane (Me3TACN) in the gas phase.

  Rapid communications in mass spectrometry : RCM 20050101

• Catalytic oxidative ring opening of THF promoted by a carboxylate-bridged diiron complex, triarylphosphines, and dioxygen.

  Inorganic chemistry 20040712

• Formation and reaction of O=MnV species in the oxidation of phenolic substrates with H2O2 catalysed by the dinuclear manganese(IV) 1,4,7-trimethyl-1,4,7-triazacyclononane complex [MnIV2(mu-O)3(TMTACN)2](PF6)2.

  Organic & biomolecular chemistry 20040421

• Coordination chemistry of silanedithiolato ligands derived from cyclotrisilathiane: synthesis and structures of complexes of iron(II), cobalt(II), palladium(II), copper(I), and silver(I).

  Inorganic chemistry 20030825

• Azo dye oxidation with hydrogen peroxide catalysed by manganese 1,4,7-triazacyclononane complexes in aqueous solution.

  Organic & biomolecular chemistry 20030507

• Acid-base equilibrium of aqua-chromium-dioxolene complexes aimed at formation of oxo-chromium complexes.

  Inorganic chemistry 20021104

• A silica gel-supported ruthenium complex of 1,4,7-trimethyl-1,4,7-triazacyclononane as recyclable catalyst for chemoselective oxidation of alcohols and alkenes by tert-butyl hydroperoxide.

  The Journal of organic chemistry 20021101

• Synthesis and alkali metal ion-binding properties of a chromium(III) triacetylide complex.

  Journal of the American Chemical Society 20021002

• A cyano-bridged single-molecule magnet: slow magnetic relaxation in a trigonal prismatic MnMo(6)(CN)(18) cluster.

  Journal of the American Chemical Society 20020703

• Giant metal-cyanide coordination clusters: tetracapped edge-bridged cubic Cr(12)Ni(12)(CN)(48) and double face-centered cubic Cr(14)Ni(13)(CN)(48) species.

  Inorganic chemistry 20020617

• Tetracyanide-bridged divanadium complexes: redox switching between strong antiferromagnetic and strong ferromagnetic coupling.

  Journal of the American Chemical Society 20020410

• Catalytic oxidation by a carboxylate-bridged non-heme diiron complex.

  Journal of the American Chemical Society 20020320

• Nickel(II)-molybdenum(III)-cyanide clusters: synthesis and magnetic behavior of species incorporating [(Me(3)tacn)Mo(CN)(3)].

  Journal of the American Chemical Society 20020313

• Tris(pyridinealdoximato)metal complexes as ligands for the synthesis of asymmetric heterodinuclear Cr(III)M species [M = Zn(II), Cu(II), Ni(II), Fe(II), Mn(II), Cr(II), Co(III)]: a magneto-structural study.

  Inorganic chemistry 20011217

• Long-range exchange interactions and integer-spin S(t) = 2 EPR spectra of a Cr(III)Zn(II)Cr(III) species with multiplet mixing.

  Inorganic chemistry 20010312

• Tmtacn, tacn, and triammine complexes of (eta 6-arene)OsII: syntheses, characterizations, and photosubstitution reactions (tmtacn = 1,4,7-trimethyl-1,4,7-triazacyclononane; tacn = 1,4,7-triazacyclononane).

  Inorganic chemistry 20010212